Application of iron(III) complexes, tris(2,2'-bipyridyl)iron(III) perchlorate and some iron(III) solvates, for oxidative aryl-aryl coupling reactions.
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چکیده
منابع مشابه
Synthesis, Spectral Characterization, Antimicrobial and Aryl-Aryl Coupling Studies of some Azo Schiff base Ru(III) Complexes
Ru(III) Azo Schiff base complexes of the type has been synthesized by the condensation of o-phenylenediamine and 3,5-diaminobenzoic acid with 2-hydroxy naphthaldehyde /vanillin. The complexes were characterized by elemental analyses, molar conductance, magnetic susceptibility, IR, UV spectral data and thermal analyses. The elemental analysis of the complexes confirmed the stoichiometry of the c...
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Transition metal-catalyzed C–C cross-coupling reactions are among the most powerful transformations known to organic chemists, and have received considerable attention over the last decades. For this reason, the development of mild chemo-, regio-, and stereoselective syntheses for the formation of carbon–carbon bonds catalyzed by metal complexes is of great interest. These methods have had a pr...
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Aryl lithium reagents formed by directed lithiation reactions undergo transmetallation with copper(I) salts to form organocuprates, which may be efficiently oxidized to yield ortho-substituted biaryls.
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Palladium-catalyzed alkynylation has emerged as one of the most reliable methods for the synthesis of alkynes which are often used in natural product syntheses and material science. An efficient method for coupling alkynyltrifluoroborates with various aryl bromides in the presence of a palladium catalyst has been developed using microwave irradiation. The microwave reactions are rapid and effic...
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ژورنال
عنوان ژورنال: Chemical and Pharmaceutical Bulletin
سال: 1986
ISSN: 0009-2363,1347-5223
DOI: 10.1248/cpb.34.3159